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Lipids
Each type of lipid has a slightly different structure, but they all possess
a large number of C - H bonds which makes them a primarily
non-polar group of molecules. All the C-H bonds also makes them very Energy-rich.
| There
are three different functions for lipids in our bodies: |
- Energy
storage
- Forming the
membranes around our cells.
- Hormones
and vitamins
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On function for Lipids
is that of Energy storage. Lipids contain a lot of calories in
a small space. Since Lipids are generally insoluble in polar substances
such as water, they are stored in special ways in you body's cells. Lipids
can also function as structural components in the cell. Phospholipids
are the major building blocks of cell membranes. Lipids are also used
as hormones that play roles in regulating our Physiology (metabolism).
Most lipids are composed of some sort of fatty acid arrangement. The
fatty
acids are composed of methylene (or Methyl) groups, and are not water
soluble.
Fatty
Acids:
The lipid
building blocks: The
common building block for most of the different types of lipids is the
fatty acid. Fatty acids are composed of a chain of methylene
groups with a Carboxyl functional group at
one end.
Saturated
and unsaturated FAs form different types of lipids.
The methyl chain is
the fatty part, the Carboxyl, the acid. The fatty acid chains are usually
between 10 and 20 Carbon atoms long. The fatty "tail" is non-polar
(Hydrophobic) while the Carboxyl "head" is a little polar
(Hydrophillic).
Fatty acids
can be saturated (meaning they have
as many hydrogens bonded to their carbons as possible) or unsaturated
(with one or more double bonds connecting their carbons, hence fewer hydrogens).
A fat is a solid at room temperature, while an oil is a
liquid under the same conditions. The
fatty acids in oils are mostly unsaturated, while those in fats are mostly
saturated.
Compare the fatty
acid on the left to the one above. A double bond connects the two, red
Carbon atoms. Since Carbon forms four bonds, these Carbon atoms are only
bonded to one Hydrogen each. This is not as many as the fatty acid above,
so this fatty acid is called unsaturated. (monounsaturated).
The double bond also
gives unsaturated fatty acids a bend in the methylene chain. This bend
affects the chemical characteristics of unsaturated fatty acids. The straighter,
saturated Fatty Acids all line-up very close together and stick to each
other. These interactions make them less fluid and more solid (more
like Fat). The bent unsaturated Fatty Acids can't get as close together,
so they don't stick as much. They are more fluid (more like Oil).
Triglycerides:
Energy Storage,
Three fatty acids bonded to Glycerol. Triglycerides
are Energy-storage molecules. They are formed by connecting three
fatty acids (shown in black) to the red part of the molecule on
the left, Glycerol. As you can imagine, the
three fatty acids together, contain a lot of Energy (aka Calories). Fat
has a lot of calories.
The flabby stuff most
of us have on certain parts of our bodies is cells filled with triglycerides.
In trigylcerides,
a fatty acid is joined to each of the three Carbons of Glycerol by Dehydration
Synthesis to form a molecule which stores a lot of calories in a small
space.
move on to more lipid
stuff. 
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Olestra - Part
Lipid, Part Carbohydrate
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